In the title compound, [Fe(C 5 H 5 )(C 19 H 15 BN)(C 18 H 15 P)(CO)], the Fe II atom is coordinated by a carbonyl group, a triphenylphosphine ligand, an isocyanotriphenylborate ligand and a cyclopentadienyl ligand in a piano-stool structure. Two crystallographically independent molecules exist in th
Carbonyl(η5-cyclopentadienyl)(3,5-dimethylpyridine-κN)(triethylsilyl)iron(II)
✍ Scribed by Itazaki, Masumi ;Ueda, Kensuke ;Nakazawa, Hiroshi
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 112 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Fe(C 5 H 5 )(C 6 H 15 Si)(C 7 H 9 N)(CO)], the Fe atom is coordinated by carbonyl, 3,5-dimethylpyridine, triethylsilyl and cyclopentadienyl ligands in a typical pianostool structure. The Fe-Si and Fe-N distances are 2.3341 (9) and 1.982 (2) A ˚, respectively.
📜 SIMILAR VOLUMES
Bis[(g 5 -cyclopentadienyl)tris(diethyl phosphito)j 3 P,P 0 0 0 ,P 0 0 00 0 0 -cobaltate(III)-j 3 O,O 0 0 0 ,O 0 0 00 0 0 ]cobalt(II)
In the title centrosymmetric dinuclear iron(II) compound, [Fe 2 (C 12 H 8 N 5 ) 2 (NCS) 2 (CH 4 O) 2 ], the deprotonated 3,5-di-2pyridyl-1,2,4-triazole ligand uses a pair of N pyridyl /N triazolyl atoms to chelate one metal atom and the other pair of N pyridyl / N triazolyl atoms to chelate the othe