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Bis(μ-3,5-di-2-pyridyl-1,2,4-triazolato-κ4N1,N5:N2,N3)bis[(methanol-κO)(thiocyanato-κN)iron(II)]

✍ Scribed by Jiang, Gang-Biao ;Zeng, Xin-Nian ;Fang, Yu-Sheng ;Zeng, Ming-Hua ;Ng, Seik Weng

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 958 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807039177

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✦ Synopsis

In the title centrosymmetric dinuclear iron(II) compound, [Fe 2 (C 12 H 8 N 5 ) 2 (NCS) 2 (CH 4 O) 2 ], the deprotonated 3,5-di-2pyridyl-1,2,4-triazole ligand uses a pair of N pyridyl /N triazolyl atoms to chelate one metal atom and the other pair of N pyridyl / N triazolyl atoms to chelate the other metal atom. Each Fe atom is octahedrally coordinated by four N atoms surrounding the metal center in a square-planar environment. Above and below this plane are located the N atom of the thiocyanate anion and the O atom of the methanol molecule. Intermolecular O-HÁ Á ÁN hydrogen bonding gives rise to a layer motif.

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