Bis[(η5-cyclopentadienyl)tris(diethyl phosphito)-κ3P,P′,P′′-cobaltate(III)-κ3O,O′,O′′]cobalt(II)
✍ Scribed by Weberski, Michael P. ;McLauchlan, Craig C.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 174 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Bis[(g 5 -cyclopentadienyl)tris(diethyl phosphito)j 3 P,P 0 0 0 ,P 0 0 00 0 0 -cobaltate(III)-j 3 O,O 0 0 0 ,O 0 0 00 0 0 ]cobalt(II)
📜 SIMILAR VOLUMES
The title complex, [Co(CH 3 ) 2 (C 8 H 7 O 3 )(C 3 H 9 P) 2 ], crystallizes with two molecules in the asymmetric unit. The Co III centre has a distorted octahedral geometry in both molecules.
In the title compound, [CoI(C 7 H 8 O 2 )(C 3 H 9 P) 3 ], the cobalt center is in a distorted octahedral geometry.
Single-crystal X-ray study T = 113 K Mean '(C±C) = 0.006 A Ê Disorder in main residue R factor = 0.047 wR factor = 0.133 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.