)(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)]
Bis(3,5-dicarboxybenzoato-κ2O,O′)(1,10-phenanthroline)cobalt(II)
✍ Scribed by Han, Jin-Yu ;Wei, Wen-Ying ;Dou, Xiao ;Chang, He-Ying
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 190 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
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Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1
The two independent molecules of the title compound, [Ba(C~7~H~5~O~3~)~2~(C~12~H~8~N~2~)~2~(H~2~O)~2~], are disposed about a pseudo-inversion centre. The Ba atom is eight-coordinate in a square-antiprismatic geometry in both molecules.
The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co