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(2-Formyl-6-methoxy­phenolato-κ2O,O′)-cis-dimethyl-trans-bis­(trimethyl­phosphine-κP)cobalt(III)

✍ Scribed by Zhou, Jin ;Fang, Shimin ;Sun, Hongjian ;Li, Xiaoyan

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
149 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Co(CH 3 ) 2 (C 8 H 7 O 3 )(C 3 H 9 P) 2 ], crystallizes with two molecules in the asymmetric unit. The Co III centre has a distorted octahedral geometry in both molecules.

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In the title compound, [Co(CH 3 ) 2 (C 13 H 13 O 2 )(C 3 H 9 P) 2 ], the Co is at the centre of a distorted octahedron, with two methyl groups trans to the chelating 2-formyl-4-phenylcyclohexen-1olato ligand forming the equatorial plane and two trimethylphosphine groups in the axial positions. The c

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