(1η5-Cyclopentadienyl)(μ-disulfur dinitrido)(triphenylphosphino-2κP)cobalt(II)gold(I) perchlorate
✍ Scribed by Slawin, Alexandra M. Z. ;Woollins, J. Derek
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 166 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [{Au(C~18~H~15~P)}Co(C~5~H~5~)(N~2~S~2~)]ClO~4~, has a planar CoS~2~N~2~ ring and a close-to-linear N—Au—P angle [176.54 (11)°].
📜 SIMILAR VOLUMES
In the title structure, [CoRu(C 10 H 20 )Cl(C 17 H 14 P) 2 ]PF 6 Á-0.5CH 2 Cl 2 , the Ru atom is coordinated by a pentamethylcyclopentadienyl ring, one Cl atom and two P atoms of the chelating 1,1 0 -bis(diphenylphosphino)cobaltocenium ligand, giving a three-legged piano-stool geometry. The solvent
The title compound, [Mo 2 (P 2 )(CO) 4 (C 8 H 9 O 2 ) 2 ], which was synthesized by refluxing a toluene solution of [( 5 -CH 3 CH 2 O 2 CC 5 H 4 ) 2 Mo 2 (CO) 6 ] and P 4 under N 2 , has a tetrahedral [Mo 2 P 2 ] core with a transverse coordinated P 2 ligand and an [( 5 -CH 3 CH 2 O 2 CC 5 H 4 )Mo(C
Dianiline-1jN,2jN-bis[3,4(g 5 )-pentamethylcyclopentadienyl]tetra-l 3 -sulfidotetrahedro-dicopper(I)dimolybdenum(V) bis(perchlorate) aniline hemisolvate