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Dianiline-1κN,2κN-bis­[3,4(η5)-pentamethyl­cyclo­penta­dien­yl]tetra-μ3-sulfido-tetra­hedro-dicopper(I)dimolybdenum(V) bis­(perchlorate) aniline hemisolvate

✍ Scribed by Ren, Zhi-Gang ;Lang, Jian-Ping ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
164 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

Dianiline-1jN,2jN-bis[3,4(g 5

)-pentamethylcyclopentadienyl]tetra-l 3 -sulfidotetrahedro-dicopper(I)dimolybdenum(V) bis(perchlorate) aniline hemisolvate

📜 SIMILAR VOLUMES

Bis[1,2(η5)-penta­methyl­cyclo­penta­die
Bis[1,2(η5)-penta­methyl­cyclo­penta­dienyl]dipyridine-3κN,4κN-tetra-μ3-sulfido-tetra­hedro-dimolybdenum(V)dicopper(I) bis­(perchlorate)
✍ Ren, Zhi-Gang ;Lang, Jian-Ping 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 253 KB

The cluster dication of the title compound, [Cu~2~Mo~2~(C~10~H~15~)~2~S~4~(C~5~H~5~N)~2~](ClO~4~)~2~, has [(η^5^-C~5~Me~5~)~2~Mo~2~(μ-S)~2~S~2~] units linked to Cu(py)^+^ units (py is pyridine) by Cu—S bonds and features a cubane-like [Mo~2~S~4~Cu~2~] core framework. The Cu atom shows a distorted te