The preparation of the mixed-metal cluster, [Fe 2 Os(C 5 H 9 N) 2 -(CO) 10 ], and its crystal structure at 100 K are reported. This complex, along with the cluster in the preceding paper, are the first structurally characterized substitution derivatives of Fe 2 Os(CO) 12 . The isonitrile ligands ado
Tetrakis(tert-butyl isocyanide-2κC)dichloro-1κCl,3κCl-di-μ-cyano-1κN:2κC;2κC:3κN-bis[1,3(η4)-cycloocta-1,5-diene]dirhodium(I)ruthenium(II)
✍ Scribed by Imhof, Wolfgang ;Halbauer, Kathi ;Görls, Helmar
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 232 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The preparation of the mixed-metal cluster, [Fe 2 Os(C 5 H 9 N)-(CO) 11 ], and its crystal structure at 100 K are reported. This complex, along with the cluster reported in the following paper, are the first structurally characterized substitution derivatives of Fe 2 Os(CO) 12 . The isonitrile ligan
In the molecule of the title compound, [FeRu(C 3 H 5 )(C 5 H 5 )-(C 10 H 15 )(CO) 4 ]PF 6 , two metal centers are bridged by an allyl chain, resulting in a chiral heterobimetallic molecular ion, with hexafluorophosphate as counter-ion. Both enantiomers are present in the crystal structure, forming a