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Bis(tert-butyl isocyanide)-1κ2C-di-μ-carbonyl-2:3κ4C-octacarbonyl-1κ2C,2κ3C,3κ3C-triangulo-diironosmium

✍ Scribed by Evans, Cameron ;Farrugia, Louis J. ;Tegel, Marcus

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 134 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806004247

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✦ Synopsis

The preparation of the mixed-metal cluster, [Fe 2 Os(C 5 H 9 N) 2 -(CO) 10 ], and its crystal structure at 100 K are reported. This complex, along with the cluster in the preceding paper, are the first structurally characterized substitution derivatives of Fe 2 Os(CO) 12 . The isonitrile ligands adopt axial positions on the osmium centre and the cluster is isostructural with the Fe 2 Ru analogue.

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✦ Synopsis

Bis(tert-butyl isocyanide)-1κ2C-di-μ-carbonyl-2:3κ4C-octacarbonyl-1κ2C,2κ3C,3κ3C-triangulo-diironosmium