The preparation of the mixed-metal cluster, [Fe 2 Os(C 5 H 9 N) 2 -(CO) 10 ], and its crystal structure at 100 K are reported. This complex, along with the cluster in the preceding paper, are the first structurally characterized substitution derivatives of Fe 2 Os(CO) 12 . The isonitrile ligands ado
Decacarbonyl-1κ3C,2κ3C,3κ4C-[μ-1-diphenylarsino-2-(diphenylphosphino)ethane-1:2κ2As:P]-triangulo-triruthenium(0)
✍ Scribed by bin Shawkataly, Omar ;Chong, Mei-Lin ;Fun, Hoong-Kun ;Didierjean, Claude ;Aubry, André
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 196 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The preparation of the mixed-metal cluster, [Fe 2 Os(C 5 H 9 N)-(CO) 11 ], and its crystal structure at 100 K are reported. This complex, along with the cluster reported in the following paper, are the first structurally characterized substitution derivatives of Fe 2 Os(CO) 12 . The isonitrile ligan
The title compound, [Sn~4~(C~9~H~12~N)~4~S~6~]·CHCl~3~, consists of four [2-(Me~2~NCH~2~)C~6~H~4~]Sn units bridged by six S atoms along with a disordered solvent molecule. The cage-like structure has two four-membered Sn~2~S~2~ rings linked by two S atoms in an Sn~4~S~6~ skeleton. The asymmetry of t