The title compound, [Sn 4 (CH 3 ) 8 (C 6 H 5 N 2 O 2 ) 4 O 2 ]Á6H 2 O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn 2 O 2 ring. The Snatom coordination geometry might be regarded as very distorted SnO 3 C 2 trigonal-bipyramidal or possibly as g
Octabutyl-1κ2C,2κ2C,3κ2C,4κ2C-di-μ3-oxo-1:2:3κ3O;2:3:4κ2O-di-μ2-phenoxy-1:2κ2O;3:4κ2O-diphenoxy-1κO,4κO-tetratin(IV)
✍ Scribed by Beckmann, Jens ;Dakternieks, Dainis ;Duthie, Andrew ;Jurkschat, Klaus ;Schürmann, Markus
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 266 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.035 wR factor = 0.099 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Di-l 2 -acetato-1:2j 3 O,O 0 0 0 :O;2:3j 3 O:-O,O 0 0 0 -tetrakis(l 2 -2-hydroxybenzoato)-1:2j 4 O:O 0 0 0 ;2:3j 4 O:O 0 0 0 -bis(1,10-phenanthroline)-1j 2 N,N 0 0 0 ;3j 2 N,N 0 0 0 -trizinc(II)
The preparation of the mixed-metal cluster, [Fe 2 Os(C 5 H 9 N) 2 -(CO) 10 ], and its crystal structure at 100 K are reported. This complex, along with the cluster in the preceding paper, are the first structurally characterized substitution derivatives of Fe 2 Os(CO) 12 . The isonitrile ligands ado