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tert-Butyl isocyanide-1κC-di-μ-carbonyl-2:3κ4C-nona­carbonyl-1κ3C,2κ3C,3κ3C-triangulo-diironosmium

✍ Scribed by Evans, Cameron ;Farrugia, Louis J. ;Tegel, Marcus

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
135 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The preparation of the mixed-metal cluster, [Fe 2 Os(C 5 H 9 N)-(CO) 11 ], and its crystal structure at 100 K are reported. This complex, along with the cluster reported in the following paper, are the first structurally characterized substitution derivatives of Fe 2 Os(CO) 12 . The isonitrile ligand adopts an axial position on the osmium centre and the cluster is isostructural with the Fe 2 Ru analogue. metal-organic papers Acta Cryst. (2006). E62, m475-m477 Tegel et al. [Fe 2 Os(C 5 H 9 N)(CO) 11 ] m477

📜 SIMILAR VOLUMES

Bis(tert-butyl isocyanide)-1κ2C-di-μ-car
Bis(tert-butyl isocyanide)-1κ2C-di-μ-carbonyl-2:3κ4C-octa­carbonyl-1κ2C,2κ3C,3κ3C-triangulo-diironosmium
✍ Evans, Cameron ;Farrugia, Louis J. ;Tegel, Marcus 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 134 KB

The preparation of the mixed-metal cluster, [Fe 2 Os(C 5 H 9 N) 2 -(CO) 10 ], and its crystal structure at 100 K are reported. This complex, along with the cluster in the preceding paper, are the first structurally characterized substitution derivatives of Fe 2 Os(CO) 12 . The isonitrile ligands ado