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Dicarbon­yl(η5-1-carboxy­cyclo­penta­dien­yl)methyl­iron(II)

✍ Scribed by Bala, Muhammad D. ;Munyaneza, Apollinaire ;Coville, Neil J.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
212 KB
Volume
61
Category
Article
ISSN
1600-5368

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Dicarbon­yl(η5-penta­methyl­cyclo­penta­
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In the title compound, [Fe(C 10 H 15 )(C 18 H 15 P)(CO) 2 ]PF 6 , the Fe II atom is coordinated by two carbonyl groups, a triphenylphosphine ligand and a pentamethylcyclopentadienyl ligand in a typical piano-stool structure.

(η5-Cyclo­penta­dien­yl)[η4-(exo-5-pheny
✍ Li, Li-Yan ;Gan, Quan ;Meng, Xiang-Gao ;Yu, Guang-Ao ;Liu, Sheng-Hua 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

In the crystal structure of the title compound, [Co(C 5 H 5 )-(C 13 H 10 )], the Co atom is connected to two five-membered rings. Both rings are disordered and were refined using a split model.

Dicarbon­yl(η5-cyclo­penta­dien­yl)(1-ph
✍ Reiss, Guido J. ;Ganter, Christian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 189 KB

The cation of the title compound, C 19 H 18 FeO 2 P + ÁBF 4 À or [Fe(C 5 H 5 )(C 12 H 13 P)(CO) 2 ]BF 4 , features a typical half-sandwich-type structure with four ligands roughly giving a tetrahedral coordination of the Fe ion.