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Azido­(2,2′-bipyridine)(η5-penta­methylcyclo­penta­dien­yl)iridium(III) hexa­fluoro­phosphate

✍ Scribed by Suzuki, Takayoshi

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
192 KB
Volume
61
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

Dicarbon­yl(η5-penta­methyl­cyclo­penta­
Dicarbon­yl(η5-penta­methyl­cyclo­penta­dien­yl)(triphenyl­phosphine)iron(II) hexa­fluoro­phosphate
✍ Nakazawa, Hiroshi ;Itazaki, Masumi ;Owaribe, Mari 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 166 KB

In the title compound, [Fe(C 10 H 15 )(C 18 H 15 P)(CO) 2 ]PF 6 , the Fe II atom is coordinated by two carbonyl groups, a triphenylphosphine ligand and a pentamethylcyclopentadienyl ligand in a typical piano-stool structure.

[μ-1κC1:2(C2,C3-η)-All­yl]tetra­carbonyl
[μ-1κC1:2(C2,C3-η)-All­yl]tetra­carbonyl-1κ2C,2κ2C-(1η5-cyclo­penta­dien­yl)(2η5-penta­methyl­cyclo­penta­dien­yl)rutheniumiron hexa­fluoro­phosphate
✍ Friedrich, Holger B. ;Changamu, Evans O. ;Rademeyer, Melanie 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB

In the molecule of the title compound, [FeRu(C 3 H 5 )(C 5 H 5 )-(C 10 H 15 )(CO) 4 ]PF 6 , two metal centers are bridged by an allyl chain, resulting in a chiral heterobimetallic molecular ion, with hexafluorophosphate as counter-ion. Both enantiomers are present in the crystal structure, forming a