trans-(Acetonitrile)bis[1,2-bis(diphenylphosphino)ethane-κ2P,P′](phenylethynyl)ruthenium(II) hexafluorophosphate ethanol hemisolvate
✍ Scribed by Willis, Anthony C. ;Powell, Clem E. ;Humphrey, Mark G.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 158 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [RuCl(C~26~H~24~P)~2~(H~2~O)]PF~6~·1.5CH~2~Cl~2~·0.5H~2~O, the complex Ru^II^ cation is in a slightly distorted octahedral environment, chelated by two bis(diphenylphosphino)ethane ligands, with a water molecule and a chloride anion in a mutually __cis__ geometry completing th
In the title structure, [CoRu(C 10 H 20 )Cl(C 17 H 14 P) 2 ]PF 6 Á-0.5CH 2 Cl 2 , the Ru atom is coordinated by a pentamethylcyclopentadienyl ring, one Cl atom and two P atoms of the chelating 1,1 0 -bis(diphenylphosphino)cobaltocenium ligand, giving a three-legged piano-stool geometry. The solvent
Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.008 A Ê Disorder in solvent or counterion R factor = 0.036 wR factor = 0.084 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.