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{μ-9,10-Bis­[(n-propyl­amino)­methyl]­anthracene-κ2N:N′}bis{bis­[6-chloro-2-(di­phenyl­phosphino)­pyridine-κP]copper(I)} diperchlorate

✍ Scribed by Xu, Feng-Bo ;Xu, Hu ;Leng, Xue-Bing ;Song, Hai-Bin ;Li, Qing-Shan ;Zou, Ru-Yi ;Zhang, Zheng-Zhi

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
304 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu 2 (C 15 H 13 ClP) 4 (C 30 H 28 N 2 )](ClO 4 ) 2 , was synthesized by the reaction of 9,10-bis[(n-propylamino)methyl]anthracene and 6-chloro-2-(diphenylphosphino)pyridine with [Cu(CH 3 CN) 4 ]ClO 4 . The Cu atoms adopt a trigonal±planar geometry and the cation is centrosymmetric. Three-layer %±% stacking interactions are observed between the anthracene and pyridyl rings.

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Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.015 A Ê R factor = 0.068 wR factor = 0.185 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.