𝔖 Bobbio Scriptorium
✦   LIBER   ✦

{μ-2-[1-(N,N-Dimethyl­amino)­eth­yl]ferrocene-1,1′-diylbis(diphenyl­phosphine)-κ2P:P′}bis­[thio­cyanato­gold(I)]

✍ Scribed by Sam, Zolisa A. ;Elmroth, Sofi K. C. ;Roodt, Andreas ;Muller, Alfred J.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
203 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Au~2~Fe(C~38~H~37~NP~2~)(SCN)~2~], is a dinuclear gold(I) complex containing an unsymmetrical bidentate ferrocenyl–phosphine ligand. Selected geometrical parameters for the compound are Au—P = 2.265 (2) and 2.260 (3) Å, Au—S = 2.327 (3) and 2.313 (3) Å, and P—Au—S = 175.61 (9) and 176.86 (9)°.

📜 SIMILAR VOLUMES

Di-μ-thio­cyanato-bis­{[1,1′-bis­(di­phe
Di-μ-thio­cyanato-bis­{[1,1′-bis­(di­phenyl­phosphino)­ferrocene-κ2P,P′]­copper(I)} di­chloro­methane disolvate
✍ Li, Dan ;Luo, Ya-Fang ;Wu, Tao ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

Single-crystal X-ray study T = 123 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.056 wR factor = 0.166 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Chloro­(2-{[N-(4-methoxy­benz­yl)methyl­
Chloro­(2-{[N-(4-methoxy­benz­yl)methyl­amino]meth­yl}ferrocene-κ2N,C1)(triphenyl­phosphine-κP)palladium(II)
✍ Wang, Hong-Xing ;Wu, Hong-Fei ;Gao, Ren-Qing ;Geng, Feng-Ying ;Li, Ying-Jie 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 154 KB

In the title compound, [PdCl{Fe(C 5 H 5 )(C 15 H 17 NO)}-(C 18 H 15 P)] or [FePd(C 5 H 5 )(C 15 H 17 NO)Cl(C 18 H 15 P)], the Pd II atom is in a slightly distorted square-planar environment. The dihedral angle between the two cyclopentadienyl rings of the ferrocenyl group is 6.4 (1) .