Chloro(2-{[N-(4-methoxybenzyl)methylamino]methyl}ferrocene-κ2N,C1)(triphenylphosphine-κP)palladium(II)
✍ Scribed by Wang, Hong-Xing ;Wu, Hong-Fei ;Gao, Ren-Qing ;Geng, Feng-Ying ;Li, Ying-Jie
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 154 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [PdCl{Fe(C 5 H 5 )(C 15 H 17 NO)}-(C 18 H 15 P)] or [FePd(C 5 H 5 )(C 15 H 17 NO)Cl(C 18 H 15 P)], the Pd II atom is in a slightly distorted square-planar environment. The dihedral angle between the two cyclopentadienyl rings of the ferrocenyl group is 6.4 (1) .
📜 SIMILAR VOLUMES
The asymmetric unit of the title compound, [FePd-(C 5 H 5 )(C 11 H 15 NO)Cl(C 18 H 15 P)]ÁCH 2 Cl 2 , contains two molecular palladium complexes and two dichloromethane solvent molecules. The Pd atoms have approximately square planar configurations. Intermolecular O-HÁ Á ÁCl hydrogen bonds stabilize