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Chloro­{1-[(1-hydroxy­methyl-2-methyl­prop­yl)imino­meth­yl]ferrocenyl-κ2C,N}(triphenyl­phosphine-κP)palladium(II) dichloro­methane solvate

✍ Scribed by Qian, Heng-Yu ;Cui, Xiu-Ling

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
192 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The asymmetric unit of the title compound, [FePd-(C 5 H 5 )(C 11 H 15 NO)Cl(C 18 H 15 P)]ÁCH 2 Cl 2 , contains two molecular palladium complexes and two dichloromethane solvent molecules. The Pd atoms have approximately square planar configurations. Intermolecular O-HÁ Á ÁCl hydrogen bonds stabilize the crystal structure.

📜 SIMILAR VOLUMES

Chloro­(2-{[N-(4-methoxy­benz­yl)methyl­
Chloro­(2-{[N-(4-methoxy­benz­yl)methyl­amino]meth­yl}ferrocene-κ2N,C1)(triphenyl­phosphine-κP)palladium(II)
✍ Wang, Hong-Xing ;Wu, Hong-Fei ;Gao, Ren-Qing ;Geng, Feng-Ying ;Li, Ying-Jie 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 154 KB

In the title compound, [PdCl{Fe(C 5 H 5 )(C 15 H 17 NO)}-(C 18 H 15 P)] or [FePd(C 5 H 5 )(C 15 H 17 NO)Cl(C 18 H 15 P)], the Pd II atom is in a slightly distorted square-planar environment. The dihedral angle between the two cyclopentadienyl rings of the ferrocenyl group is 6.4 (1) .

Acetato­[1-(oxazolin-2-yl­methyl-κN)-1H-
Acetato­[1-(oxazolin-2-yl­methyl-κN)-1H-indolyl-κC2](tri­phenyl­phosphine)­palladium(II) di­chloro­methane solvate
✍ Cowley, Andrew R. ;Cooper, Richard I. ;Capito, Elena ;Brown, John M ;Ricci, Alfr 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 250 KB

The title compound, [Pd(C 2 H 3 O 2 )(C 18 H 15 P)(C 12 H 11 N 2 O)]Á-CH 2 Cl 2 , crystallizes readily from a mixture of dichloromethane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N-substituent in five-membered-ring heterocycles [Nonoyama & Nakaji