The title compound, [Pd(C 2 H 3 O 2 )(C 18 H 15 P)(C 12 H 11 N 2 O)]Á-CH 2 Cl 2 , crystallizes readily from a mixture of dichloromethane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N-substituent in five-membered-ring heterocycles [Nonoyama & Nakaji
Chloro{1-[(dimethylamino)methyl-κN]-1H-indolyl-κC2}(triphenylphosphine-κP)palladium(II) dichloromethane solvate
✍ Scribed by Cooper, Richard I. ;Cowley, Andrew R. ;Capito, Elena ;Brown, John M. ;Ricci, Alfredo
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 173 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.041 wR factor = 0.088 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.031 wR factor = 0.072 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.