𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Acetato­[1-(oxazolin-2-yl­methyl-κN)-1H-indolyl-κC2](tri­phenyl­phosphine)­palladium(II) di­chloro­methane solvate

✍ Scribed by Cowley, Andrew R. ;Cooper, Richard I. ;Capito, Elena ;Brown, John M ;Ricci, Alfredo

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
250 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Pd(C 2 H 3 O 2 )(C 18 H 15 P)(C 12 H 11 N 2 O)]Á-CH 2 Cl 2 , crystallizes readily from a mixture of dichloromethane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N-substituent in five-membered-ring heterocycles [Nonoyama & Nakajima (1998). Polyhedron, 18, 533-543].

📜 SIMILAR VOLUMES

Chloro­{1-[(1-hydroxy­methyl-2-methyl­pr
Chloro­{1-[(1-hydroxy­methyl-2-methyl­prop­yl)imino­meth­yl]ferrocenyl-κ2C,N}(triphenyl­phosphine-κP)palladium(II) dichloro­methane solvate
✍ Qian, Heng-Yu ;Cui, Xiu-Ling 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 192 KB

The asymmetric unit of the title compound, [FePd-(C 5 H 5 )(C 11 H 15 NO)Cl(C 18 H 15 P)]ÁCH 2 Cl 2 , contains two molecular palladium complexes and two dichloromethane solvent molecules. The Pd atoms have approximately square planar configurations. Intermolecular O-HÁ Á ÁCl hydrogen bonds stabilize

Di­chloro{1-[2-(di­phenyl­phosphino-κP)­
Di­chloro{1-[2-(di­phenyl­phosphino-κP)­ethyl]-1,3-di­hydro-3-(2,4,6-tri­methyl­phenyl)-2H-imidazol-2-yl­idene-κC}palladium(II) diethyl ether solvate
✍ Lee, Hon Man ;Chiu, Pei Ling 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 213 KB

Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.031 wR factor = 0.080 Data-to-parameter ratio = 20.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.