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Di­chloro{1-[2-(di­phenyl­phosphino-κP)­ethyl]-1,3-di­hydro-3-(2,4,6-tri­methyl­phenyl)-2H-imidazol-2-yl­idene-κC}palladium(II) diethyl ether solvate

✍ Scribed by Lee, Hon Man ;Chiu, Pei Ling


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
213 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.031 wR factor = 0.080 Data-to-parameter ratio = 20.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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The title compound, [Pd(C 2 H 3 O 2 )(C 18 H 15 P)(C 12 H 11 N 2 O)]Á-CH 2 Cl 2 , crystallizes readily from a mixture of dichloromethane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N-substituent in five-membered-ring heterocycles [Nonoyama & Nakaji