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μ-4,4′-Di-4-pyridyl­diazene-κ2N:N′-bis{[1,1,1-tris­(di­phenyl­phosphino­methyl)­ethane-κP3]copper(I)} bis­(tetra­fluoro­borate) di­chloro­methane solvate

✍ Scribed by Yu, Ming-Ming ;Li, Zhan-Xian ;Fu, Wen-Fu ;Zhang, Jun-Feng


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
219 KB
Volume
61
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê Disorder in solvent or counterion R factor = 0.067 wR factor = 0.210 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.008 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.036 wR factor = 0.087 Data-to-parameter ratio = 23.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org

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The title compound, {[Ag(bpe)](OTf)} n (OTf = tri¯uoromethanesulfonate) or {[Ag(C 12 H 12 N 2 )](CF 3 O 3 S)} n , has been prepared from the reaction of 1,2-bis(4-pyridyl)ethane (bpe) and Ag(CF 3 SO 3 ) in MeCN/H 2 O. The Ag I atom is twocoordinate in a slightly distorted linear arrangement, and the