μ-1,2-Ethanediylbis(diphenylphosphine)-κ2P:P′-bis{acetato[1,2-ethanediylbis(diphenylphosphine)-κ2P,P′]copper(I)} diethyl ether disolvate
✍ Scribed by Morawitz, Thorsten ;Lerner, Hans-Wolfram ;Bru Roig, Miriam ;Bolte, Michael
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 176 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In polymeric [Ag(C 2 F 3 O 2 )(C 26 H 24 P 2 )] n , the carboxylate is monodentate to silver, and the two diphosphine ligands that occupy different positions of 1 site symmetry link the Ag(C 2 O 2 F 3 ) units into a chain. The Ag atom shows trigonalplanar coordination.
In the title compound, [Cu 2 I 2 (C 21 H 21 P) 3 ], one Cu I atom is coordinated by one tri-p-tolylphosphine and two iodide ligands in a distorted trigonal-planar geometry, whereas the other Cu I atom is coordinated by two phosphine and two iodide ligands in a distorted tetrahedral geometry.
Bis[l-bis(diphenylphosphino)methane-j 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoroborate) dichloromethane disolvate