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Tritium NMR spectroscopy of steroids

✍ Scribed by Carel W. Funke; Frans M. Kasperen; Jan Wallaart; Gerard N. Wagenaars

Publisher: John Wiley and Sons
Year: 1983
Tongue: French
Weight: 320 KB
Volume: 20
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2580200709

No coin nor oath required. For personal study only.

✦ Synopsis

The H NMR spectra of a series of 7 steroids tritiated at C ( l ) , C ( 2 ) , C ( 6 ) , C ( 7 ) , C ( 9 ) and C ( 1 6 ) yield quantitative information on the 3H distribution i n these compounds. Deuterated chloroform i s not a good solvent to examine the regio-and stereospecificity of the labelling process for acid labile positions such as C(2) in a 3-oxosteroid and C ( 6) in a 8-0x0-0 -steroid.

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