Single-crystal X-ray study T = 295 K Mean (C-C) = 0.007 A R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Tris(triphenylphosphine)copper(I) hexafluorophosphate
✍ Scribed by Healy, Peter C. ;Hanna, John V.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 308 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Crystals of the title compound, (C 6 F 5 ) 3 P O or C 18 H 15 OP, have two independent molecules in the asymmetric unit, with average P O and PÐC bond lengths of 1.467 (2) and 1.817 (2) A Ê , respectively, and an average O PÐC angle of 112.9 (1) .
The Cu atom in the title compound, [Cu(C 5 H 11 NO 2 ) 4 ](PF 6 ) 2 , shows square-planar coordination. The asymmetric unit comprises one eighth of the molecular formula.
The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1
The title compound, [Cu(C 24 H 16 N 2 )(C 18 H 15 P) 2 ]BF 4 , consists of mononuclear Cu(PPh 3 ) 2 (NN) + and BF 4 À ions (NN is 4,7diphenyl-1,10-phenanthroline). The Cu I atom is four-coordinated by two P atoms of PPh 3 groups and two N donors of two NN ligands to form a tetrahedral coordination g