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Tris­(tri­phenyl­phosphine)copper(I) hexa­fluoro­phosphate

✍ Scribed by Healy, Peter C. ;Hanna, John V.


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
308 KB
Volume
59
Category
Article
ISSN
1600-5368

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The title compound, [Cu(C 24 H 16 N 2 )(C 18 H 15 P) 2 ]BF 4 , consists of mononuclear Cu(PPh 3 ) 2 (NN) + and BF 4 À ions (NN is 4,7diphenyl-1,10-phenanthroline). The Cu I atom is four-coordinated by two P atoms of PPh 3 groups and two N donors of two NN ligands to form a tetrahedral coordination g