The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1
Tris(pentafluorophenyl)phosphine oxide
✍ Scribed by Nicholson, Brian K. ;Thwaite, Susanna E.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 153 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Crystals of the title compound, (C 6 F 5 ) 3 P O or C 18 H 15 OP, have two independent molecules in the asymmetric unit, with average P O and PÐC bond lengths of 1.467 (2) and 1.817 (2) A Ê , respectively, and an average O PÐC angle of 112.9 (1) .
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 230 K Mean '(C±C) = 0.002 A Ê R factor = 0.031 wR factor = 0.083 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The crystal structure of bis(triphenylphosphine)iminium cyclopentadienyltricarbonylmolybdate, [PPN][Mo(CO) 3 ( 5 -C 5 H 5 )] (PPN + = [(PPh 3 ) 2 N] + , C 36 H 30 NP 2 ), is reported. The anion is con®gured in the `piano-stool' arrangement while the cation adopts a bent con®guration about the PÐNÐP