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trans-Carbonyl­chloro­bis[tris­(penta­fluoro­phenyl)phosphine)]rhodium(I)

✍ Scribed by Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
124 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (13) , P-Rh-P = 169.38 (4) and Rh-C O = 176.7 (4) . The effective cone angles ( E ) for the phosphine ligands were calculated to be 172 and 173 .

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