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trans-Bis(benzyl­diphenyl­phosphine)carbonyl­chloro­rhodium(I)

✍ Scribed by Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
231 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, trans-[RhCl(C~19~H~17~P)~2~(CO)], selected geometrical parameters are: Rh—P = 2.3204 (5) and 2.3365 (5) Å, Rh—Cl = 2.3687 (5) Å and Rh—C = 1.8007 (15) Å, and P—Rh—P = 179.005 (16)°, P—Rh—Cl = 88.807 (15)° and 90.529 (15)°, and Rh—C[triple-bond]O = 176.43 (13)°. The effective cone angles for the phosphine ligands were calculated to be 156 and 160°.

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