The title compound, [RhCl(PBz 3 ) 2 (CO)] [PBz 3 = tribenzylphosphine, P(C 7 H 7 ) 3 ], which is the ®rst reported tribenzyl-phosphine±rhodium(I) structure, has pseudo-square-planar coordination geometry, with RhÐP bond distances of 2.3164 (15) and 2.3156 (16) A Ê . The RhÐCl, RhÐC and CÐ O bond dis
trans-Carbonylchlorobis(tri-m-tolylphosphino)rhodium(I) dichloromethane solvate
✍ Scribed by Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 136 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.008 A Ê R factor = 0.038 wR factor = 0.090 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [RhCl{P(OC 8 H 9 ) 3 } 2 (CO)], where P(OC 8 H 9 ) 3 is tris(2,6-dimethylphenyl)phosphite, crystallizes with two independent molecules, both disordered over inversion centres. The Rh1ÐP1 and Rh2ÐP2 bond distances are 2.3097 (7) and 2.2995 (7) A Ê , respectively. The effective con
The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1