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trans-Carbonyl­chloro­bis­[tris(2,6-di­methyl­phenyl)­phosphito]­rhodium(I)

✍ Scribed by Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
143 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [RhCl{P(OC 8 H 9 ) 3 } 2 (CO)], where P(OC 8 H 9 ) 3 is tris(2,6-dimethylphenyl)phosphite, crystallizes with two independent molecules, both disordered over inversion centres. The Rh1ÐP1 and Rh2ÐP2 bond distances are 2.3097 (7) and 2.2995 (7) A Ê , respectively. The effective cone angle for the phosphite ligands was calculated as 182 .

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.027 wR factor = 0.041 Data-to-parameter ratio = 26.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.