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{2,6-Bis­[(di­phenyl­phosphino)­methyl]­phenyl}chloro­platinum(II)

✍ Scribed by Fischer, Steffen ;Wendt, Ola F.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
223 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.027 wR factor = 0.041 Data-to-parameter ratio = 26.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 145 K Mean '(C±C) = 0.020 A Ê R factor = 0.092 wR factor = 0.221 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

trans-Di-μ-chloro-bis­[(di­methyl sulfox
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✍ Nilsson, Patrik ;Wendt, Ola F. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 180 KB

The title compound, [Pt 2 Cl 2 (C 6 H 5 ) 2 (C 2 H 6 OS) 2 ] or [Pt("-Cl)Ph(dmso)] 2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is c