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trans-Di-μ-chloro-bis­[(di­methyl sulfoxide-κS)­phenyl­platinum(II)]

✍ Scribed by Nilsson, Patrik ;Wendt, Ola F.

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
180 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Pt 2 Cl 2 (C 6 H 5 ) 2 (C 2 H 6 OS) 2 ] or [Pt("-Cl)Ph(dmso)] 2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is centrosymmetric, thus necessitating a trans con®guration, with one dmso and one phenyl ligand coordinated to each Pt atom. The two PtÐCl, the PtÐS and the PtÐC distances are 2.366 (2), 2.475 (2), 2.192 (2) and 1.997 (7) A Ê , respectively.

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