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[μ-2,3,5,6-Tetrakis(2-pyridyl)­pyrazine]­bis­[chloro­platinum(II)] bis­[tri­chloro­(di­methyl sulfoxide-κS)­platinate(II)]

✍ Scribed by Sakai, Ken ;Kurashima, Mai

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
344 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

Tetrakis(2-pyridyl)pyrazine]bis-[chloroplatinum(II)] bis[trichloro(dimethyl sulfoxide-jS)platinate(II)]

📜 SIMILAR VOLUMES

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The title compound, [Pt 2 Cl 2 (C 6 H 5 ) 2 (C 2 H 6 OS) 2 ] or [Pt("-Cl)Ph(dmso)] 2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is c

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The crystal structure of the title compound, [Cd 2 Cl 4 -(C 6 H 9 N 3 S) 2 ], has been determined. The compound is isomorphous with the previously reported Cu II and Co II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atom

[μ-N,N,N′,N′-Tetrakis(2-pyridyl­methyl)-
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✍ Yoon, Doo-Cheon ;Oh, Chang-Eon ;Lee, Uk 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 142 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.009 A Ê R factor = 0.057 wR factor = 0.136 Data-to-parameter ratio = 19.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.