The title compound, [Pt 2 Cl 2 (C 6 H 5 ) 2 (C 2 H 6 OS) 2 ] or [Pt("-Cl)Ph(dmso)] 2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is c
trans(Cl,Namino)-Chloro(dimethyl sulfoxide-κS)[tris(2-pyridylmethyl)amine-κ4N]ruthenium(II) trichlorotris(dimethyl sulfoxide-κS)ruthenate(II)
✍ Scribed by Masui, Dai ;Yamaguchi, Motowo ;Yamagishi, Takamichi
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 146 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
trans(Cl,N amino )-Chloro(dimethyl sulfoxide-jS)[tris(2-pyridylmethyl)amine-j 4 N]ruthenium(II) trichlorotris(dimethyl sulfoxide-jS)ruthenate(II)
📜 SIMILAR VOLUMES
Tetrakis(2-pyridyl)pyrazine]bis-[chloroplatinum(II)] bis[trichloro(dimethyl sulfoxide-jS)platinate(II)]
The title ruthenium±carbonyl complex, [Ru(C 12 H 20 N 4 )-(C 18 H 15 P)(CO)]Cl 2 Á1.5CH 2 Cl 2 , crystallizes in the triclinic space group P1 as a monomeric complex.
The title compound, [CuCl 2 (C 11 H 24 N 2 )], crystallizes as fourcoordinate monomers with distorted square-planar geometry. The complex is chiral and forms racemic crystals. Molecules which have an S-con®guration at nitrogen have a !conformation of the ®ve-membered chelate ring, and those with R-c