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Di-μ-chloro-bis{chloro­[3,5-di­methyl-1-(thio­carbamoyl)­pyrazole-κ2N2,S]­cadmium(II)}

✍ Scribed by Radosavljević Evans, Ivana ;Mészáros Szécsényi, Katalin ;Leovac, Vukadin M.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
205 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The crystal structure of the title compound, [Cd 2 Cl 4 -(C 6 H 9 N 3 S) 2 ], has been determined. The compound is isomorphous with the previously reported Cu II and Co II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atoms. The structure is stabilized by a two-dimensional network of hydrogen bonds involving the terminal Cl atoms as acceptors and thiocarbamoyl group N atoms as donors.

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Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.041 wR factor = 0.100 Data-to-parameter ratio = 25.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.