[1,2-Bis(methylthio)ethane-κ2S,S′]dichlorozinc(II)
✍ Scribed by Parvez, Masood ;Clark, Peter D. ;Yao, Hong
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 159 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The central Zn atom in the structure of the title compound, [ZnCl 2 (C 4 H 10 S 2 )], exhibits a distorted tetrahedral geometry and is coordinated by two Cl and two S atoms, with ZnÐCl distances of 2.203 (2) and 2.212 (2) A Ê , and ZnÐS distances of 2.390 (2) and 2.459 (2) A Ê . The angles ClÐZnÐCl and SÐ ZnÐS are 123.28 (7) and 90.68 (6) , respectively, while the ClÐZnÐS angles are in the range 106.13 (6)±112.69 (7) .
📜 SIMILAR VOLUMES
The crystal structure of the title compound, [Cd 2 Cl 4 -(C 6 H 9 N 3 S) 2 ], has been determined. The compound is isomorphous with the previously reported Cu II and Co II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atom
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.093 Data-to-parameter ratio = 27.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Zn(C 12 H 10 N 2 O 2 S) 2 (C 2 H 6 OS)], is monomeric with the Zn atom in a ®ve-coordinate environment. The geometry of the polyhedron is distorted trigonal bipyramidal, with angles of the equatorial atoms about the central Zn atom in the range 77.84 (10)±126.66 (12) A Ê . The O
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.041 wR factor = 0.100 Data-to-parameter ratio = 25.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.