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(Di­methyl sulfoxide-κS)­bis­[2′-(3-methyl­thio­phen-2-yl­methyl­ene)­furan-2-carbohydr­azido]­zinc(II)

✍ Scribed by Ali, Hapipah ;Omar, Sh. Rohaiza S. ;Yusof, M. Sukeri M. ;Yamin, Bohari M.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
376 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Zn(C 12 H 10 N 2 O 2 S) 2 (C 2 H 6 OS)], is monomeric with the Zn atom in a ®ve-coordinate environment. The geometry of the polyhedron is distorted trigonal bipyramidal, with angles of the equatorial atoms about the central Zn atom in the range 77.84 (10)±126.66 (12) A Ê . The OÐZnÐO axial bond angle is 173.12 (12) .

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.015 A Ê R factor = 0.057 wR factor = 0.194 Data-to-parameter ratio = 14.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.