Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate
✍ Scribed by Fujihara, Takashi ;Sugaya, Tomoaki ;Nagasawa, Akira ;Nakayama, Juzo
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 360 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Zn(C 12 H 10 N 2 O 2 S) 2 (C 2 H 6 OS)], is monomeric with the Zn atom in a ®ve-coordinate environment. The geometry of the polyhedron is distorted trigonal bipyramidal, with angles of the equatorial atoms about the central Zn atom in the range 77.84 (10)±126.66 (12) A Ê . The O
The crystal structure of the title compound, [Cd 2 Cl 4 -(C 6 H 9 N 3 S) 2 ], has been determined. The compound is isomorphous with the previously reported Cu II and Co II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atom