The central Zn atom in the structure of the title compound, [ZnCl 2 (C 4 H 10 S 2 )], exhibits a distorted tetrahedral geometry and is coordinated by two Cl and two S atoms, with ZnÐCl distances of 2.203 (2) and 2.212 (2) A Ê , and ZnÐS distances of 2.390 (2) and 2.459 (2) A Ê . The angles ClÐZnÐCl
Dichlorobis(1,3-dimethylthiourea-κS)zinc(II)
✍ Scribed by Burrows, Andrew D. ;Harrington, Ross W. ;Mahon, Mary F.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 202 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Molecules of the title compound, [HgI 2 (C 14 H 11 ClN 2 OS) 2 ], are discrete and have crystallographic twofold rotation symmetry, with the Hg atom in a four-coordinate environment. The geometry of the central Hg atom is distorted tetrahedral with bond angles in the range 99.00 (8)±137.56 (3) .
The crystal structure of the title compound, [Cd 2 Cl 4 -(C 6 H 9 N 3 S) 2 ], has been determined. The compound is isomorphous with the previously reported Cu II and Co II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atom
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.033 wR factor = 0.103 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.