Bis(o-chlorophenylbenzoylthiourea-κS)diiodomercury(II)
✍ Scribed by Yusof, M. Sukeri M. ;Yamin, Bohari M. ;Kassim, Mohammad B.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 229 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Molecules of the title compound, [HgI 2 (C 14 H 11 ClN 2 OS) 2 ], are discrete and have crystallographic twofold rotation symmetry, with the Hg atom in a four-coordinate environment. The geometry of the central Hg atom is distorted tetrahedral with bond angles in the range 99.00 (8)±137.56 (3) .
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 123 K Mean '(C±C) = 0.003 A Ê R factor = 0.026 wR factor = 0.063 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Pt 2 Cl 2 (C 6 H 5 ) 2 (C 2 H 6 OS) 2 ] or [Pt("-Cl)Ph(dmso)] 2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is c
The central Zn atom in the structure of the title compound, [ZnCl 2 (C 4 H 10 S 2 )], exhibits a distorted tetrahedral geometry and is coordinated by two Cl and two S atoms, with ZnÐCl distances of 2.203 (2) and 2.212 (2) A Ê , and ZnÐS distances of 2.390 (2) and 2.459 (2) A Ê . The angles ClÐZnÐCl