Dibromodicarbonylbis(triphenylphosphine)ruthenium(II) dichloromethane solvate
✍ Scribed by Lozano Diz, Enrique ;Therrien, Bruno ;Neels, Antonia ;Süss-Fink, Georg
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 193 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.008 A Ê R factor = 0.038 wR factor = 0.090 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
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The structure of the title monomeric phosphosilicate, C 54 H 45 O 4 PSi 3 Á0.263CH 2 Cl 2 or (Ph 3 SiO) 3 POÁ0.263CH 2 Cl 2 , is reported and is the first of a phosphosiloxane molecule with the general formula (R 3 SiO) 3 PO. Although the three P V -O-Si angles are remarkably similar [143.57 (16), 1
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