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trans-Carbonylchlorobis[diphenyl(4-tolyl)phosphine]rhodium(I)

✍ Scribed by Kirsten, Leo ;Steyl, Gideon ;Roodt, Andreas

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 137 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806023798

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✦ Synopsis

The title compound, [RhCl(C~19~H~17~P)~2~(CO)], can be characterized as a Vaska-type complex containing a diphenyl(4-tolyl)phosphine ligand. The rhodium(I) metal centre has a square-planar coordination. The molecule is disordered, with the Rh atom lying on an inversion centre. The most important bond lengths and angles include Rh—P = 2.3315 (9) Å, Rh—Cl(trans CO) = 2.405 (2) Å, Rh—C(carbonyl) = 1.724 (11) Å and Rh—C—O = 178.0 (6)°.

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✦ Synopsis

trans-Carbonylchlorobis[diphenyl(4-tolyl)phosphine]rhodium(I)