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trans-Dichloro­bis[diphen­yl(p-tol­yl)­phos­phine]­palladium(II)

✍ Scribed by Steyl, Gideon ;Kirsten, Leo ;Roodt, Andreas

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
167 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The centrosymmetric title compound, [PdCl~2~(C~19~H~17~P)~2~], crystallizes with a square-planar geometry about the Pd^II^ metal centre. The most important bond distances include Pd—P (trans P) of 2.3404 (9) Å and Pd—Cl (trans Cl) of 2.2977 (12) Å. Weak intra- and intermolecular hydrogen bonding is observed in the solid-state structure between the chloro and phenyl H atoms. This weak intermolecular hydrogen-bonding pattern forms a one-dimensional chain along the b axis.

📜 SIMILAR VOLUMES

trans-Carbonyl­chloro­bis[diphen­yl(4-to
trans-Carbonyl­chloro­bis[diphen­yl(4-tol­yl)phosphine]rhodium(I)
✍ Kirsten, Leo ;Steyl, Gideon ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 137 KB

The title compound, [RhCl(C~19~H~17~P)~2~(CO)], can be characterized as a Vaska-type complex containing a diphenyl(4-tolyl)phosphine ligand. The rhodium(I) metal centre has a square-planar coordination. The molecule is disordered, with the Rh atom lying on an inversion centre. The most important bon