The structure of the title compound, [PdCl 2 (C 10 H 10 N 2 ) 2 ], has the palladium center situated on a center of inversion. The imidazole group is twisted from the square coordination plane with a C-N-Pd-Cl torsion angle of 31.93 (12) ; this is different from the angle reported in closely related
trans-Dichlorobis[(S)-(–)-1-(1-naphthyl)ethylamine]palladium(II)
✍ Scribed by Vázquez, Jaime ;Bernès, Sylvain ;Hernández, Guadalupe ;Aguilar, Hilda ;Gutiérrez, René
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 220 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title centrosymmetric complex, trans-[PtCl 2 (C 6 H 10 N 2 ) 2 ], the Pt II centre is coordinated by two piperidine-1-carbonitrile ligands and two chloro ligands, resulting in a typical squareplanar geometry. The C-N distance between the nitrile and piperidine group [1.306 (4) A ˚] clearly in
In the structure of the title compound, [PdCl 2 (C 5 H 10 N 2 ) 2 ], at 150 K, the Pd atom is situated on a centre of inversion. The geometry of the complex is similar to that of trans-bis(1benzylimidazole)dichloropalladium(II).