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Dichloro­bis(1-methyl-1,4,5,6-tetra­hydro­pyrimidine)palladium(II)

✍ Scribed by Chang, Chiung-Fang ;Lee, Hon Man

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
61 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the structure of the title compound, [PdCl 2 (C 5 H 10 N 2 ) 2 ], at 150 K, the Pd atom is situated on a centre of inversion. The geometry of the complex is similar to that of trans-bis(1benzylimidazole)dichloropalladium(II).

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The title compound, C 14 H 14 N 2 O 3 , possesses C s symmetry, with the central CH 2 and C O atoms of the tetrahydropyrimidin-2-one group lying on the mirror plane. The molecule is bowshaped, with two symmetry-related intramolecular CÐHÁ Á ÁO hydrogen bonds. In the crystal structure, the molecules

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The title compound, C~26~H~26~N~2~O~7~, is a thiamidine derivative. Geometric parameters are in the usual ranges. The crystal packing is stabilized by a classical N—H...O hydrogen bond, several weak C—H...O hydrogen bonds and a π–π stacking interaction.

6,9-Dichloro-1,2,3,4-tetra­hydro­acridin
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