[1,2-Bis(phenylsulfanyl)benzene]dichloropalladium(II)
✍ Scribed by Takeda, Nobuhiro ;Shimizu, Daisuke ;Sasamori, Takahiro ;Tokitoh, Norihiro
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 335 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [PdCl 2 (C 7 H 9 NS) 2 ], the Pd atom lies on a center of inversion and is coordinated by two chloride anions and two N atoms from two benzenamine ligands to give rise to a square-planar coordination geometry for the Pd atom. A layer structure results from N-HÁ Á ÁCl hydrogen b
In the title compound, C 14 H 14 S 2 , there is a centre of inversion at the mid-point of the central C-C bond. Excluding H atoms, the molecule adopts an anti conformation, with a planar -S-CH 2 -CH 2 -S-spacer unit. The dihedral angle between the phenyl ring and the S-C-C-S chain is 84.52 (18) .
In the title compound, C 24 H 22 Cl 2 N 2 O 2 S, synthesized from 2-(2-methoxyphenylsulfanyl)benzoyl chloride and 1-(2,3dichlorophenyl)piperazine, the piperazine ring adopts a normal chair conformation.