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Dichloro­bis[4-(methyl­sulfan­yl)aniline-κN]palladium(II)

✍ Scribed by Pan, Yue-Li ;Zhao, Feng ;Yang, Song


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
141 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title complex, [PdCl 2 (C 7 H 9 NS) 2 ], the Pd atom lies on a center of inversion and is coordinated by two chloride anions and two N atoms from two benzenamine ligands to give rise to a square-planar coordination geometry for the Pd atom. A layer structure results from N-HÁ Á ÁCl hydrogen bonds.


📜 SIMILAR VOLUMES


trans-Bis(aniline-κN)dichloro­bis(ethano
✍ Clegg, William ;Martin, Nicola C. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 214 KB

The title compound, [CoCl~2~(C~6~H~7~N)~2~(C~2~H~6~O)~2~], was obtained unintentionally as the product of an attempted synthesis of a polycarboxylate-bridged network complex of cobalt(II) using aniline as a base to deprotonate the organic acid. The molecule is centrosymmetric, so pairs of equivalent

Dichloro­{(E)-2,4,6-trimethyl-N-[1-(2-py
✍ Hsueh, Mao-Lin ;Su, Sheng-Yuan ;Lin, Chu-Chieh 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 146 KB

The title complex, [PdCl 2 (C 16 H 18 N 2 )]ÁC 2 H 3 N, contains a slightly distorted square planar Pd II center coordinated by two N and two Cl atoms. The crystal packing is stabilized by C-HÁ Á ÁCl interactions.

trans-Di­chloro­bis(3,4-lutidine-κN)­pal
✍ Sui-Seng, Christine ;Rochon, Fernande D. ;Zargarian, Davit 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 159 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.032 wR factor = 0.084 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.