Dichlorobis[4-(methylsulfanyl)aniline-κN]palladium(II)
✍ Scribed by Pan, Yue-Li ;Zhao, Feng ;Yang, Song
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 141 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [PdCl 2 (C 7 H 9 NS) 2 ], the Pd atom lies on a center of inversion and is coordinated by two chloride anions and two N atoms from two benzenamine ligands to give rise to a square-planar coordination geometry for the Pd atom. A layer structure results from N-HÁ Á ÁCl hydrogen bonds.
📜 SIMILAR VOLUMES
The title compound, [CoCl~2~(C~6~H~7~N)~2~(C~2~H~6~O)~2~], was obtained unintentionally as the product of an attempted synthesis of a polycarboxylate-bridged network complex of cobalt(II) using aniline as a base to deprotonate the organic acid. The molecule is centrosymmetric, so pairs of equivalent
The title complex, [PdCl 2 (C 16 H 18 N 2 )]ÁC 2 H 3 N, contains a slightly distorted square planar Pd II center coordinated by two N and two Cl atoms. The crystal packing is stabilized by C-HÁ Á ÁCl interactions.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.032 wR factor = 0.084 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.