In the title crystal structure, C 14 H 14 S 2 , L 2 , the molecules lie on crystallographic inversion centers. The phenyl rings are nearly perpendicular to the planar S-C-C-S group of atoms.
1,2-Bis(phenylsulfanyl)ethane
✍ Scribed by Hou, Bao-Hong ;Zhou, Li-Na ;Yin, Qiu-Xiang ;Wang, Jing-Kang ;Chen, Wei
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 109 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 14 H 14 S 2 , there is a centre of inversion at the mid-point of the central C-C bond. Excluding H atoms, the molecule adopts an anti conformation, with a planar -S-CH 2 -CH 2 -S-spacer unit. The dihedral angle between the phenyl ring and the S-C-C-S chain is 84.52 (18) .
📜 SIMILAR VOLUMES
The title compound, C 16 H 18 S 2 (or L 6 ), crystallizes with two half-molecules in the asymmetric unit and each independent molecule lies about a crystallographic center of symmetry. The aliphatic segment of this ligand is in an all-trans conformation.