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[μ-1,2-Bis(phenyl­sulfan­yl)ethane-κ2S:S′]bis­[dibromo­mercury(II)]

✍ Scribed by Gong, Jun-Bo ;Zhou, Li-Na ;Chen, Wei

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
230 KB
Volume
62
Category
Article
ISSN
1600-5368

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✍ Yu, Qun ;Tao, Ying ;Li, Jian-Rong 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 100 KB

The title complex, [HgBr 2 (C 19 H 24 S 2 )] n , has a single-chain structure in which adjacent HgBr 2 units are linked by bridging ligands. The Hg II centre has a distorted tetrahedral coordination environment formed by two Br À anions and two S atoms from distinct ligands.

1,2-Bis(phenyl­sulfan­yl)ethane
1,2-Bis(phenyl­sulfan­yl)ethane
✍ Hou, Bao-Hong ;Zhou, Li-Na ;Yin, Qiu-Xiang ;Wang, Jing-Kang ;Chen, Wei 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 109 KB

In the title compound, C 14 H 14 S 2 , there is a centre of inversion at the mid-point of the central C-C bond. Excluding H atoms, the molecule adopts an anti conformation, with a planar -S-CH 2 -CH 2 -S-spacer unit. The dihedral angle between the phenyl ring and the S-C-C-S chain is 84.52 (18) .

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✍ Cui, Yun-Cheng ;Che, Guang-Bo ;Lin, Xian-Feng ;Liu, Chun-Bo 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

The title complex, [Hg~2~Br~4~(C~7~H~16~S~2~)]~n~, has a chain structure. Two bridging Br atoms and two terminal Br atoms coordinate to two Hg^II^ atoms, forming an (HgBr~2~)~2~ dimer, which is located on an inversion center. The 1,3-bis(ethylsulfanyl)propane ligands, which lie on a twofold axis, br